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Chlorite


A group of common sheet silicate minerals


Chlorite

Chlorite: Chlorite from Quebec, Canada. This specimen is approximately 3 inches (7.6 centimeters) across.

What is Chlorite?

"Chlorite" is the name of a group of common sheet silicate minerals that form during the early stages of metamorphism. Most chlorite minerals are green in color, have a foliated appearance, perfect cleavage, and an oily to soapy feel. They are found in igneous, metamorphic and sedimentary rocks.

Chlorite minerals are found in rocks altered during deep burial, plate collisions, hydrothermal activity, or contact metamorphism. They are also found as retrograde minerals in igneous and metamorphic rocks that have been weathered. Rocks that commonly contain abundant chlorite include greenschist, phyllite, chlorite schist, and greenstone.



Chlorite Minerals

MineralComposition
Baileychlore(Zn,Fe+2,Al,Mg)6(Al,Si)4O10(O,OH)8
BorocookeiteLi1+3xAl4-x(BSi3O10)(OH)8
Chamosite(Fe+2,Mg,Al,Fe+3)6(Si,Al)4O10(OH,O)8
Clinochlore(Mg,Fe)5Al(Si3Al)O10(OH)8
Cookeite(Al2Li)Al2(Si3AlO10)(OH)8
DonbassiteAl13(Al3Si9O30)(OH)24
FranklinfurnaceiteCa2Fe+3Mn+23Mn+3(Zn2Si2O10)(OH)8
GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8
Gonyerite(Mn,Mg)5Fe+3(Fe+3Si3O10)(OH)8
Nimite(Ni,Mg,Al)6(Si,Al)4O10(OH)8
Odinite(Fe+2,Mg,Al,Fe+3,Ti,Mn)12(Al,Si)10O25OH20
Orthochamosite(Fe+2,Mg,Fe+3)5Al(Si3AlO10)(O,OH)8
Pennantite(Mn5Al)(Si3Al)O10(OH)8
Ripidolite(Mg,Fe,Al)6(Al,Si)4O10(OH)8
SudoiteMg2(Al,Fe)3(Si3AlO10)(OH)8

Chlorite Minerals

Chlorite minerals have a generalized chemical composition of (X,Y)4-6(Si,Al)4O10(OH,O)8. The "X" and "Y" in the formula represent ions, which might include: Fe+2, Fe+3, Mg+2, Mn+2, Ni+2, Zn+2, Al+3, Li+1, or Ti+4. The composition and physical properties of chlorites vary as these ions substitute for one another in solid solution.

The most common chlorite minerals are clinochlore, pennantite, and chamosite. A more comprehensive list of chlorite minerals and their chemical compositions is shown in the green table on this page.

Chlorite layering

Chlorite: A side view of chlorite showing its foliated appearance. Specimen is from Quebec, Canada and is approximately 3 inches (7.6 centimeters) across.



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Where Does Chlorite Form?

Chlorite minerals most often form in rock environments where minerals are altered by heat, pressure, and chemical activity. These generally have a temperature less than a few hundred degrees and are within a few miles of Earth's surface.

Chlorite minerals often form in clay-rich sedimentary rocks that are buried in deep sedimentary basins or subjected to regional metamorphism at a convergent plate boundary. Chlorite that forms here is usually associated with biotite, muscovite, garnet, staurolite, andalusite, or cordierite. Metamorphic rocks rich in chlorite might include phyllite and chlorite schist.

Another environment of chlorite mineral formation is in oceanic crust descending into subduction zones. Here, amphiboles, pyroxenes, and micas are altered into chlorite.

Chlorite minerals also form during the hydrothermal, metasomatic, or contact metamorphism. These chlorite minerals are often found in fractures, solution cavities, or the vesicles of igneous rocks.

Physical Properties of Chlorite

Chemical Classification Silicate
Color Various shades of green. Rarely yellow, white, pink, black
Streak Greenish to greenish gray
Luster Vitreous, pearly, dull
Diaphaneity Transparent, translucent, opaque
Cleavage Perfect in one direction
Mohs Hardness 2 to 3
Specific Gravity 2.6 to 3.3
Diagnostic Properties Color, hardness, foliated appearance, feels slightly greasy
Chemical Composition A generalized formula: (X,Y)4-6(Si,Al)4O10(OH,O)8

The "X" and "Y" in the formula represent ions, which might include: Fe+2, Fe+3, Mg+2, Mn+2, Ni+2, Zn+2, Al+3, Li+1, or Ti+4. The composition and physical properties of chlorites vary as these ions substitute for one another in solid solution.
Crystal System Monoclinic
Uses Very few industrial uses. Used as a filler and as a constituent of clay.

Physical Properties of Chlorites

Members of the chlorite mineral group are typically green in color, have a foliated appearance, perfect cleavage, and an oily or soapy feel. Their variable chemical composition gives them a range of hardness and specific gravity. This makes them difficult to differentiate in hand specimen.

Recognizing a mineral as a member of the chlorite group is usually easy. However, placing a specific name on it can be difficult. Detailed optical, chemical, or x-ray analysis is usually required for positive identification. The name "chlorite" is often used in classrooms and the field because the minerals are difficult or impossible to identify. As a result, the individual chlorite minerals are poorly known.

Uses of Chlorite

Chlorite is a mineral with a low potential for industrial use. It does not have physical properties that make it suited for a particular use, and it does not contain constituents that make it a target of mining. When found, chlorite is usually intimately intermixed with other minerals, and the cost of separation would be high. As a result, chlorite is not mined and processed for any specific use. Its major use is as a coincidental constituient in crushed stone.



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