An extreme igneous rock with large crystals and rare minerals
Article by: Hobart M. King, Ph.D., RPG
What is Pegmatite?
Pegmatites are extreme igneous rocks that form during the final stage of a magma’s crystallization. They are extreme because they contain exceptionally large crystals and they sometimes contain minerals that are rarely found in other types of rocks.
To be called a "pegmatite," a rock should be composed almost entirely of crystals that are at least one centimeter in diameter. The name "pegmatite" has nothing to do with the mineral composition of the rock.
Most pegmatites have a composition that is similar to granite with abundant quartz, feldspar, and mica. These are sometimes called "granite pegmatites" to indicate their mineralogical composition. However, compositions such as "gabbro pegmatite," "syenite pegmatite," and any other plutonic rock name combined with "pegmatite" are possible.
Pegmatites are sometimes sources of valuable minerals such as spodumene (an ore of lithium) and beryl (an ore of beryllium) that are rarely found in economic amounts in other types of rocks. They also can be a source of gemstones. Some of the world’s best tourmaline, aquamarine, and topaz deposits have been found in pegmatites.
The Rock with Large Crystals
Large crystals in igneous rocks are usually attributed to a slow rate of crystallization. However, with pegmatites, large crystals are attributed to low-viscosity fluids that allow ions to be very mobile.
During the early states of a magma’s crystallization, the melt usually contains a significant amount of dissolved water and other volatiles such as chlorine, fluorine, and carbon dioxide. Water is not removed from the melt during the early crystallization process, so its concentration in the melt grows as crystallization progresses. Eventually there is an overabundance of water, and pockets of water separate from the melt.
These pockets of superheated water are extremely rich in dissolved ions. The ions in the water are much more mobile than ions in the melt. This allows them to move about freely and form crystals rapidly. This is why crystals of a pegmatite grow so large.
The extreme conditions of crystallization sometimes produce crystals that are several meters in length and weigh over one ton. For example: a large crystal of spodumene at the Etta Mine in South Dakota was 42 feet long, 5 feet in diameter and yielded 90 tons of spodumene!
Activity at the Margins of a Batholith
Pegmatites form from waters that separate from a magma in the late stages of crystallization; this activity often occurs in small pockets along the margins of a batholith. Pegmatite can also form in fractures that develop on the margins of the batholith. This is how "pegmatite dikes" are formed.
Because these dikes and pockets are small in size, the mining operations that exploit them are also small. The mining of pegmatites might be done in an underground operation that follows a dike or exploits a small pocket. It can also be done at an outcrop where the pegmatite is easily discovered by people. Pegmatites usually do not support large mining operations that employ dozens of workers and have continuous activity of many years.
Rare Minerals in Large Crystals
In the early stages of crystallization, the ions that form high-temperature minerals are depleted from the melt. Rare ions that do not participate in the crystallization of common rock-forming minerals become concentrated in the melt and in the excluded water. These ions can form the rare minerals that are often found in pegmatites. Examples are small ions such as lithium and beryllium that form spodumene and beryl; or large ions such as tantalum and niobium that form minerals such as tantalite and niobite. Rare elements concentrated in large crystals make pegmatite a potential source of valuable ore.
Uses of Pegmatite
Pegmatite rock has very few uses. However, pegmatite deposits often contain gemstones, industrial minerals, and rare minerals.
Pegmatite rock has limited use as an architectural stone. Occasionally it is encountered in a dimension stone quarry that produces granite for architectural use. If the pegmatite is sound and attractive, it might be cut into slabs and polished for building facing, countertops, tile or other decorative stone products and sold commercially as a "granite."
Some of the world’s best gemstone mines are in pegmatites. Gemstones found in pegmatite include: amazonite, apatite, aquamarine, beryl, chrysoberyl, emerald, garnet, kunzite, lepidolite, spodumene, topaz, tourmaline, zircon, and many others. Large crystals of excellent-quality material are often found in pegmatite.
Pegmatite is the host rock for many rare mineral deposits. These minerals can be commercial sources of: beryllium, bismuth, boron, cesium, lithium, molybdenum, niobium, tantalum, tin, titanium, tungsten, and many other elements. In most cases the mining operations are very small, employing less than a dozen people. If the mine contains nice crystals, the minerals are often more valuable as mineral specimens and faceting rough than being sold as an ore.
Pegmatite is often mined for industrial minerals. Large sheets of mica are mined from pegmatite. These are used to make components for electronic devices, retardation plates, circuit boards, optical filters, detector windows, and many other products. Feldspar is another mineral frequently mined from pegmatite. It is used as a primary ingredient for making glass and ceramics. It is also used as a filler in many products.
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